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聚对苯二甲酸乙二酯球晶的形态结构 被引量:1

STUDY ON THE MORPHOLOGIC STRUCTURE OF POLY (ETHYLENE TEREPHTHALATE)SPHERULITES
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摘要 用偏光显擞镜和透射电子显微镜观察了聚对苯二甲酸乙二酯(PET)溶液结晶的形态。PET在苯酚-四氯乙烷溶液结晶时,根据不同的结晶温度可产生双球晶、附生球晶、层状球晶和环状球晶结构。 The morphologic structures of poly (ethylene terephthalate)on solution crystallization have been studied by electron microscope and polarized microscope. Four types of the spherulites of PET have been observed and discussed.
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 1992年第3期114-117,共4页 Polymer Materials Science & Engineering
关键词 PET 聚酯 球晶 显微镜 poly (ethylene terephthalate ) , spherulites, electron microscope, polarized micro-scope.
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参考文献1

  • 1冯新德,饱和聚酯与缩聚反应,1986年

同被引文献8

  • 1陈俊,陈剑玲,刘正英,殷茜,黄锐.PET结晶行为研究进展[J].高分子通报,2005(1):20-24. 被引量:32
  • 2Bin Huang, John J. Walsh, Solid-phase polymerization mechanism of poly(ethylene terephthalate) affected by gas flow velocity and particle size[J]. polymer, 1998, 39(26): 6991- 6998.
  • 3Mingtao Run, Sizhu Wu, Dayu Zhang, et al. Melting behaviors and isothermal crystallization kinetics of poly ( ethylene terephthalate)/mesoporous molecular sieve composite[J]. polymer, 2005, 46:5308 - 5316.
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  • 5F J Baha' Calleja, M C Garc?'a Gutie'rtez, D R Rueda, et al. Structure development in poly( ethylene temphthalate) quenched from the melt at high cooling rates: X-ray scattering and microhardness study[J]. Polymer, 2000,41:4143 - 4148.
  • 6F Pilati, M Toselli, M Messorl, et al. On specific factors affecting the crystallization of PET: the role of carboxyl terminal groups and residual catalysts on the crystallization rate[ J]. Polymer, 1996,38 (17) :4469 -4476.
  • 7Avrami M J Chem, Polymer, 1940,8(2) : 212-224.
  • 8李力庆,周卫华,汤心颐.固相缩聚PET等温结晶动力学[J].高等学校化学学报,1992,13(6):867-869. 被引量:4

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