摘要
根据Avrami方程和瞬时传热模拟对于205℃、210℃和220℃PET等温结晶的DSC曲线进行了模拟计算,计算值与实验值吻合,且求得了主、次结晶过程的动力学参数和热焓值。
According to Avrami equation and transient heat transfer model,DSC profiles of PET isothermal crystallization,at 250℃ ,210℃ and 220℃,respectively, were simulated. The profiles of simulation are essntialy agreed with those of experiment. The kinetic parameters and the values of enthalpies, for primary and secondary stage of crystallization, were calculated.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1992年第1期96-101,共6页
Polymer Materials Science & Engineering
关键词
聚合物
对苯二甲酸
结晶
模拟计算
finite differencess .simulating calculation, transient heat transfer, isothermal crystallization.