摘要
乙醇-水混合体系中合成了15种新的稀土元素的固态配合物,通过元素分析和化学分析确定了配合物的化学组成为RE_2(BPMPPD)_3·nH_2O和Ce(BPMPPD)_2·6H_2O(BPMPPD为1,5-双(1′-苯基-3′-甲基-5′-氧代吡唑-4′-基)戊二酮-[1,5]),对配合物的荧光光谱等性质进行了研究。
The present paper covers fifteen new solid complexes of rare earth synthsized by the reaction of rare earth nitrates and (NH4)2Ce(SO4)3 with BPMPPD in the aqueous solution of ethanol. The compounds with a general formula: RE2(BPMPPD)3.nH2O(Re= La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Y. n = 3-7) ,Ce(BPMPPD)2.6H2O and (Y-Eu)2. (BPMPPD)3.8H2O(Y:95%; Eu: 5% ), were obtained and characterized by elemental analysts, chemical analysis, IR, DTA-TG, 1H NMR and fluorescence.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1992年第1期14-17,共4页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
稀土
BPMPPD
荧光
络合物
1,5-Bis-(1' -phenyl-3' -methyl-5' -pyrazolone-4' )-pentanedione-(1 ,5) (BPMPPD) , Rare earth, Fluorescence
