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Mg^(2+),Li^+//SO_4^(2-)-C_2H_5OH-H_2O体系在25℃的等温互溶度和相关系 被引量:8

Isothermal Mutual Solubility and Phase Relation of Mg^(2+),Li^+//SO_4^(2-)-C_2H_5OH-H_2O System at 25 ℃
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摘要 The isothermal mutual solubility and phase relation of MgSO 4-Li 2SO 4-C 2H 5OH-H 2O system at 25 ℃ have been investigated by using a homemade micro-equilibrium and sampling apparatus. The demixing phenomenon of the system′s at below room temperature was observed. The precise demixing composition and composition of double-saturated point of the system have been determined. A unique effect, namely additive property between MgSO 4 and Li 2SO 4 has been observed and explained in terms of "pseudo-ternary system" concept. An empirical formula has been worked out to correlate the mutual solubility. The isothermal mutual solubility and phase relation of MgSO 4-Li 2SO 4-C 2H 5OH-H 2O system at 25 ℃ have been investigated by using a homemade micro-equilibrium and sampling apparatus. The demixing phenomenon of the system′s at below room temperature was observed. The precise demixing composition and composition of double-saturated point of the system have been determined. A unique effect, namely additive property between MgSO 4 and Li 2SO 4 has been observed and explained in terms of 'pseudo-ternary system' concept. An empirical formula has been worked out to correlate the mutual solubility.
出处 《应用化学》 CAS CSCD 北大核心 2003年第2期175-177,共3页 Chinese Journal of Applied Chemistry
基金 国家自然科学基金资助项目 ( 2 99710 32 )
关键词 硫酸镁 硫酸锂 乙醇 互溶度 相关系 三元体系 相平衡 无机水盐体系 MgSO 4,Li 2SO 4,C 2H 5OH,mutual solubility,phase relation
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参考文献3

  • 1潘焕泉 高世扬.Chin J Appl Chem(应用化学)[J],1988,5(1):82-82.
  • 2夏树屏 张军 高世扬.Chin J Appl Chem(应用化学)[J],1989,6(5):63-63.
  • 3夏树屏 王桂芬.J Salt Lake Research(盐湖研究)[J],1987,1:14-14.

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