摘要
在不同溶剂中研究了硫氰酸钼(Ⅴ)络合物的性质,络合物的最大配位数为3。分别测定了在四种不同溶剂中该络合物的稳定常数和摩尔吸光系数,用萃取法研究了在不同溶剂和不同萃取剂中对硫氰酸钼(Ⅴ)络合物的萃取效果及其生成机理。
The properties of molybdenum (Ⅴ) thiocyanate complexes in four solvents and extractants have been studied. The maximium coordination number of complexes is found to be three. The stability constants and the molar extinction coefficients have been determined in the four solvents, respectively. The extractive effect and formation mechanism of these complexes have been studied in the four different solvents and extractants by pertition method.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1992年第11期1313-1316,共4页
Chinese Journal of Analytical Chemistry
关键词
硫氰酸钼
混合溶剂
萃取
络合物
Molybdenum thiocyanate
Compound solvent
Extraction
