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含氨酯基的壳聚糖衍生物的胆甾液晶螺旋性质 被引量:1

Helicoidal Properties of Cholesteric Liquid Crystalline for Urethane Derivatives of Chitosan
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摘要 用圆偏振光二向色性谱法研究了3种含氨酯基的壳聚糖衍生物的胆甾液晶螺旋性质.结果表明,3种衍生物的质量分数为65%的氯仿溶液都呈现胆甾液晶相.此外,CD谱观察结果显示侧基结构对其胆甾螺旋方向有明显的影响. The helicoidal properties of three urethane derivatives of chitosan in cholesteric liquid crystalline phase were studied by means of circular dichroism spectroscopy.The 65% chloroform solutions of all three derivatives demonstrated cholesteric liquid crystalline phase.A strong influence of the substituent on the twist sense was investigated.
出处 《吉首大学学报(自然科学版)》 CAS 2002年第4期26-29,共4页 Journal of Jishou University(Natural Sciences Edition)
基金 国家自然科学基金资助项目(29974023)
关键词 氨酯基 胆甾液晶 螺旋性质 壳聚糖衍生物 螺旋结构 圆偏光二向色性谱法 光学性质 chitosan derivatives cholesteric phase liquid crystals helicoidal structure circular dichroism
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