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共轭亚油酸乙酯与β-环糊精包结作用的紫外光谱研究 被引量:1

Studies on the Inclusion Compound of Ethyl Ester of Conjugated Linoleic Acid and β-cyclodextrin by UV Spectrophotometry
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摘要 采用 U V-910 0型紫外可见分光光度计 ,分别测定了共轭亚油酸乙酯与 β-环糊精在四种溶剂正己烷、水、甲醇、乙醇中 2 0 4-2 60 nm范围内的吸光度 ,发现 :甲醇和乙醇是较为理想的溶剂 ;即使β-CD在甲醇和乙醇中的溶解度极其微小 ,共轭亚油酸乙酯与 β-CD所形成包结物溶液的紫外吸收光谱也有较为显著的增加 ;β-环糊精对长链脂肪酸乙酯的包结能力在不同溶剂中有一定选择性 ;在水中β-环糊精对共轭亚油酸乙酯有较强的增溶作用 ,有利于乳液的稳定 。 Absorbance value of ethyl ester of conjugated linoleic acid from 204-260nm was measured by UV-9100 spectrophotometer in hexane, water, methanol and ethanol respectively. The results show that methanol and ethanol are desirably solvent. Even the solubility of β-cyclodextrin in methanol and ethanol is extremely low, which has a considerable influence on UV spectrophotometry. The inclusion ability to long chain fatty acid by β-cyclodextrin varies in different solvent. Solubilization of β-cyclodextrin to ethyl ester of conjugated linoleic acid is obvious in water which is favorable to the stability of emulsion and can prolong coacervation time of emulsion. \;
出处 《新疆师范大学学报(自然科学版)》 2002年第4期22-26,共5页 Journal of Xinjiang Normal University(Natural Sciences Edition)
关键词 紫外光谱法 共轭亚油酸乙酯 Β-环糊精 Ultraviolet-visible spectrophotometry Ethyl ester of conjugated linoleic acid β-cyclodextrin
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  • 1BENDER M L,KOMIYAMA M.Cyclodextrin reactivity and structure concepts in organic chemistry[M].Berlin:Springer,1978:6-96.
  • 2LI S,PURDY W C.Cyclodextrins and their applications in analytical chemistry[J].Chem Rev,1992,92(10):1 457-1 458.
  • 3KOONTZ J L.Formation of natamycin:cyclodextrin inclusion complexes and their characterization[J].Agric Food Chem,2003,51(12):7 106-7 108.
  • 4CHAO Jian-bin,TONG Hong-bo,HUANG Shu-ping.Preparation and study on the solid inclusion complex of sparfloxacin with β-cyclodextrin[J].Spectrochimica Acta Part A,2004,60(5):161-162.
  • 5克莱末F D.包结化合物[M].李森,译,任新民校.北京:科学出版社,1963:143-150.
  • 6TONG Lin-hui.Studies on the Lnclusion compound of conjugated linoleic acid and β-cyclodextrin by UV spectrophotometry[C]∥13th International Symposium on Macrocyclic Chemistry.Hamberg:Gesellschaft Deutscher Chemiker,1988:120-122.
  • 7DAVIES J E D.REPMEESTER J A.Physical Methods in Supramolecular Chemistry[M].Pergamon:Oxford U K,1996:426-479.
  • 8MATSUI Y,MOCHIDA K.Binding forces contributing to association of cyclodextrin with alcohol in an aqueous solution[J].Boll Chem Soc Jpn,1979,52(10):2 808-2 814.
  • 9刘书堂,郑国和,闫亚强.β-环糊精挥发油粉末化技术在中药制剂中的研究与应用[J].中草药,1997,28(12):749-751. 被引量:27
  • 10雍国平,查正根,李光水.水溶液中几种苯衍生物与β-环糊精包合物的热力学研究[J].化学研究与应用,2002,14(3):308-309. 被引量:5

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