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非晶合金NiB催化芳环及硝基的加氢性能 被引量:3

Hydrogenation of Aromatic Ring and Nitrobenzene over the Amorphous Nickel Boron Alloy
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摘要 The hydrogenation of aromatic ring and nitrobenzene over the amorphous nickel boron alloy has been investigated. The amorphous structure of the catalyst make itself exhibited a high catalytic activity in the hydrogenation of 4-ethylbenzoic acid, 4-pentylphenol and nitrobenzene. In the case of 4-pentylphenol and 4-ethylbenzoic acid, the hydrogenation conversions were 95%, 67% respectively, at 160 ℃ and hydrogen pressure of 6.0 MPa, while for nitrobenzene, the conversion was 100% at the same temperature under 4.0 MPa H 2. The hydrogenation of aromatic ring and nitrobenzene over the amorphous nickel boron alloy has been investigated. The amorphous structure of the catalyst make itself exhibited a high catalytic activity in the hydrogenation of 4-ethylbenzoic acid, 4-pentylphenol and nitrobenzene. In the case of 4-pentylphenol and 4-ethylbenzoic acid, the hydrogenation conversions were 95%, 67% respectively, at 160 ℃ and hydrogen pressure of 6.0 MPa, while for nitrobenzene, the conversion was 100% at the same temperature under 4.0 MPa H 2.
作者 杨建明 吕剑
出处 《应用化学》 CAS CSCD 北大核心 2002年第12期1200-1202,共3页 Chinese Journal of Applied Chemistry
关键词 芳环 硝基 加氢性能 NIB 非晶合金 催化氢化 镍硼合金 催化剂 amorphous nickel boron alloy,catalytic hydrogenation
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参考文献10

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