摘要
A new layered divalent metal monohydrogenphosphate [Co(H_2O)(HPO_4)]·H_2O(1) was hydrothermally synthesized from the reaction of CoCl_2·6H_2O with H_3PO_4 in the presenceof cis-Pt (NH_3)_2Cl_2 and ethylenediamine. The structure features extensive intra- and inter-layerhydrogen bonding among the hydrogenphosphate anion, the coordinated water and the crystallizationwater. X-ray crystallographic parameters for 1 are orthorhombic Pnma (#62), a = 1.7528(2), b =0.56158(7), c = 0.47867(6) nm, V = 0.47116(9) nm^3, Z = 4.
A new layered divalent metal monohydrogenphosphate [Co(H_2O)(HPO_4)]·H_2O(1) was hydrothermally synthesized from the reaction of CoCl_2·6H_2O with H_3PO_4 in the presenceof cis-Pt (NH_3)_2Cl_2 and ethylenediamine. The structure features extensive intra- and inter-layerhydrogen bonding among the hydrogenphosphate anion, the coordinated water and the crystallizationwater. X-ray crystallographic parameters for 1 are orthorhombic Pnma (#62), a = 1.7528(2), b =0.56158(7), c = 0.47867(6) nm, V = 0.47116(9) nm^3, Z = 4.
基金
theSpecialFoundationofNationalPriorityProjectfortheBasicResearch (No .G2 0 0 0 0 48)
