摘要
报道了一种亚硝酸钠介导烯烃与五硫化二磷和醇双官能化反应合成烷基二硫代磷酸酯的方法.该反应采用亚硝酸钠为肟源,在温和条件下有效合成了多种β-肟基二硫代磷酸酯化合物,具有操作简单、条件温和及无金属污染等优点.初步机理研究表明该反应经历NO正离子历程.
NaNO_(2) mediated difunctionalization of alkenes with P_(4)S_(10) and alcohols has been developed for the construction of β-oximino phosphorodithioates.This reaction utilizes NaNO_(2) as the oxime source to effectively synthesize various β-oximino phosphorodithioates under mild conditions.The method features the advantages of simple operation,mild condition,and non metal-pollution.Preliminary mechanistic studies suggest that this reaction occurs through the NO positive ion process.
作者
何卫保
贺梦云
廖琼
易荣楠
He Weibao;He Mengyun;Liao Qiong;Yi Rongnan(Research Center for Technical and Vocational Education Studies,Hunan Chemical Vocational Technology College,Zhuzhou,Hunan 412000;Key Laboratory of Food&Environment&Drug Monitoring and Testing of Universities in Hunan Province,Hunan Police Academy,Changsha 410138)
出处
《有机化学》
北大核心
2026年第2期515-522,共8页
Chinese Journal of Organic Chemistry
基金
长沙市自然科学基金(No.104872)
湖南化工职业技术学院博士科研启动基金资助项目。
