Tetranuclear N-Methyl Aminodiethylate Aluminum Complexes as Efficient Catalysts for Ring-Opening Polymerization of Substituted Epoxides

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摘要 Comprehensive Summary Polyether materials,derived from the ring-opening polymerization(ROP)of epoxides,are widely used in biomedicine and functional materials.However,due to the steric hindrance of the high-freedom substituents,monosubstituted epoxides are difficult to activate and exhibit the characteristics of being difficult to polymerize.In addition,traditional anionic ring-opening polymerization(AROP)usually has functional group tolerance problems.

作者 Yu Chen Yanwei Wang Yanping Song Xuehua Zhu Dan Yuan Yingming Yao

机构地区 State and Local Joint Engineering Laboratory for Novel Functional Department Polymeric Materials School of Chemistry and life Science

出处《Chinese Journal of Chemistry》 2025年第21期2795-2802,共8页 中国化学(英文版)

基金 support from the National Natural Science Foundation of China(22271205) PAPD is gratefully acknowledged.

关键词 Aluminum complex EPOXIDE Ring-opening polymerization POLYETHER Synergistic catalysis N O ligands Homogeneous catalysis TETRANUCLEAR

分类号 TQ316.341 [化学工程—高聚物工业] TQ426 [化学工程]

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Chinese Journal of Chemistry

2025年第21期

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Tetranuclear N-Methyl Aminodiethylate Aluminum Complexes as Efficient Catalysts for Ring-Opening Polymerization of Substituted Epoxides

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