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亚铁-甘油配合物对双氧水分解行为的影响

Effect of Ferrous Coordination Compounds on the Decomposition Behavior of Hydrogen Peroxide
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摘要 为探究近中性条件下,具有不同配合结构的亚铁-甘油配合物对双氧水分解行为的影响,合成了3种配合物M-GFe、D-GFe、T-GFe,通过红外光谱分析进行结构表征,并考察配合物用量、温度对催化双氧水的分解能力。结果表明:配合物对双氧水的催化效率依次为M-GFe>D-GFe>T-GFe;配合物D-GFe漂白后苎麻织物白度和强力分别为82.75%和481.88N。 To explore the effect of ferrous-glycerol coordination complexes with different coordination structures on the decomposition behavior of hydrogen peroxide under near-neutral conditions,three complexes(M-GFe,D-GFe,and T-GFe)were synthesized.Their structures were characterized by infrared spectroscopy,and the effects of complex dosage and temperature on the catalytic capacity for hydrogen peroxide decomposition were investigated.The results show that the catalytic efficiency of the complexes for hydrogen peroxide follows the order:M-GFe>D-GFe>T-GFe.After bleaching ramie fabric with complex D-GFe,the whiteness and strength of the fabric are 82.75%and 481.88 N.
作者 刘雪恋 夏虎 张雨萌 倪丽杰 Liu Xuelian;Xia Hu;Zhang Yumeng;Ni Lijie(School of Textile Science and Engineering,Wuhan Textile University,Wuhan,Hubei 430200,China;School of Chemistry and Chemical Engineering,Wuhan Textile University,Wuhan,Hubei 430200,China)
出处 《针织工业》 北大核心 2025年第12期48-51,共4页 Knitting Industries
基金 湖北省科技厅科技计划项目(2023BAB125) 武汉纺织大学校基金(B)(K25009)。
关键词 亚铁配合物 双氧水分解率 漂白 苎麻 Ferrous Coordination Complex Hydrogen Peroxide Decomposition Rate Bleaching Ramie Fabric
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