摘要
主要介绍了自α-二亚胺镍催化剂问世以来,科研人员通过优化催化剂中N-芳基结构以调控其催化行为的相关研究。文中以催化剂配体N-芳基结构的修饰方向为分类依据,对催化剂进行划分,逐一阐述如何通过改变催化剂配体两侧的N-芳基结构来调控催化剂催化烯烃聚合的行为,从而得到不同结构的聚合产物。
This review summarizes research progress on modulating the catalytic performance ofα-diimine nickel catalysts through optimization of the N-aryl architecture since their development.The catalysts are categorized based on modification strategies applied to the ligand's N-aryl groups.Each category is systematically elaborated to demonstrate how the catalytic performance in olefin polymerization can be regulated by tailoring the N-aryl structures,thereby enabling the production of polymeric products with distinct structures.
作者
冯涛
傅智盛
FENG Tao;FU Zhisheng(MOE Key Laboratory of Macromolecular Synthesis and Functionalization,Department of Polymer Science and Engineering,Zhejiang University-Xinglu Technology High-end Polyolefin Research&Development Center,Zhejiang University,Hangzhou 310058,China)
出处
《弹性体》
2025年第6期68-78,共11页
China Elastomerics
基金
中央高校基本科研业务费专项资金资助(226-2024-00056)。
