摘要
A recent paper published in Journal of the American Chemical Society by W.Zhang and co-workers reported a ground-breaking advance by establishing 209 Bi and 127 I ultra-wideline solid-state NMR(UW SSNMR)as powerful tools for probing bismuth and iodine ions in metal-organic frameworks(MOFs),despite the severe challenges associated with their exceptionally large quadrupolar interactions,and enabled the elucidation of key structural features that are otherwise difficult to access[1].
基金
supported by the National Natural Science Foundation of China(Grants 22472075 and 22272075).