摘要
碳硼烷作为一类独特的多面体硼簇化合物,因其三维芳香结构和多中心多电子成键,在众多领域展现出广阔的应用前景。然而,碳硼烷的B—H键较为惰性,且存在化学选择性问题,这导致碳硼烷B—H键的官能团化在合成上一直存在挑战。近年来,研究者采用光诱导策略成功实现了碳硼烷的官能团化,不仅合成了一系列碳硼烷基功能分子,也为碳硼烷的官能团化提供了新途径,为碳硼烷化学的进一步发展奠定了基础。
Carboranes,as unique polyhedral boron cluster compounds,exhibit broad application prospects in numerous fields due to their three-dimensional aromatic structures and multicenter,multielectron bonding.However,the B—H bonds in carboranes are inert and pose challenges in regioselectivity,thus making their functionalization a great challenge in synthesis.In recent years,researchers have achieved carborane functionalization by employing light-induced strategies.These studies not only open new avenues for carborane functionalization but also yield a series of functionalized molecules containing carboranyl units,thereby laying a solid foundation for the further advancement of carborane chemistry.
作者
徐圣文
杨龙龙
曹厚继
涂德双
魏星
芦昌盛
燕红
XU Shengwen;YANG Longlong;CAO Houji;TU Deshuang;WEI Xing;LU Changsheng;YAN Hong(State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China;School of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang,Henan 453007,China;AIE Institute,Guangzhou 510530,China)
出处
《无机化学学报》
北大核心
2025年第11期2187-2200,共14页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.92261202,22401141,22201067)
江苏省自然科学基金项目(No.BZ2022007,BK20241229)
中央高校基本科研业务费专项资金(No.202430362)
广州市科技计划项目(No.2023A04J0680)资助。
关键词
碳硼烷
硼簇
官能团化
光诱导
carboranes
boron clusters
functionalization
light-induced
