摘要
以4,4′-联吡啶、2-巯基苯并噻唑(HMBT)为配体,通过调控配体与镉离子(Cd^(2+))的反应比例,合成了配合物[Cd(bipy)(MBT)_(2)]_(n),并对其结构和性质进行表征.该配合物的合成作为一个综合化学实验,学生全程参与配合物合成、产物表征、性质测定等环节,培养学生的实验操作技能与综合分析能力.
The complex[Cd(bipy)(MBT)_(2)]_(n) was synthesized by reacting cadmium ions(Cd^(2+))with 4,4′-bipyridine and 2-mercaptobenzothiazole(HMBT)as ligands through precise stoichiometric control.The resulting product was systematically characterized to determine its structure and properties.Experimental results confirmed the successful formation of a novel cadmium-containing complex.This integrated experimental procedure—encompassing synthesis,characterization,and property analysis—demonstrates significant value as a comprehensive chemical pedagogy experiment.
作者
吴红燕
吴文婷
WU Hongyan;WU Wenting(School of Resource and Chemical Engineering,Sanming University,Sanming 365004,China)
出处
《许昌学院学报》
2025年第5期61-64,共4页
Journal of Xuchang University
基金
福建省自然科学基金项目(2025J011045)
2024年三明学院引进高层次人才科研启动经费支持项目(24YG05)
福建省中青年教师教育科研项目(JAT200640,B202031)。
关键词
镉配合物
综合化学实验
晶体结构
荧光性质
cadmium complex
integrated chemical experiment
crystal structure
fluorescent properties
