摘要
Beyond photothermal conversion,the surface wettability of light-absorbing materials should be also determinative to the efficiency of solar-driven interfacial steam generation(SISG).Herein,by modifying hydrophobic Cu nanoparticles(NPs)with a hydrophilic carbon(C)shell,hydrophilic Cu@C core-shell NPs were successfully fabricated and used for constructing evaporation films for SISG.In comparison to the film constructed with Cu NPs,the evaporation films constructed with Cu@C core-shell NPs exhibit much increased SISG efficiency,reaching 94.6%as high.Except for the localized surface plasmon resonance(LSPR)effect of Cu NPs ensuring the excellent photothermal conversion,it is experimentally and theoretically revealed that the surface wettability switching from hydrophobicity to hydrophilicity,as induced by C coating,is beneficial to heat transfer at the solid/liquid interface and water transport at the evaporative surface,thus improving the thermal-evaporation conversion performance for efficient SISG.However,the further thickened C shells would weaken the LSPR effect and hinder the interface heat and water transfer,leading to the decreased photothermal and thermal-evaporation conversion efficiencies,and thus the lowered SISG performances.This demonstration gives an alternative and promising access to the rational design of photothermal materials featured with switchable surface wettability ensuring interface heat and water transfer enhancement for efficient SISG.
基金
supported by the National Natural Science Foundation of China(52225606,51888103)
the Natural Science Basic Research Program of Shaanxi Province(2019JCW-10)
the“Fundamental Research Funds for the Central Universities”,and“The Youth Innovation Team of Shaanxi Universities”.
