摘要
Silicon-based materials are considered as the next generation anode to replace graphite due to their low cost and ultra-high theoretical capacity.However,significant volume expansion and contraction occur during charging and discharging processes,leading to the instability of electrode structure and susceptibility to peeling and damage,limiting its application.Constructing controllable molecular artificial solid electrolyte interphase(CMASEI)is an effective approach to address the commercialization of silicon-based anode materials[1].Improving the performance of silicon-based anodes through CMASEI is a multifaceted outcome.
基金
supported by the Nanxun Scholars Program for Young Scholars of ZJWEU(No.RC2023021315)
the start-up funding for Scientific Research for High-level Talents(No.88106324004)
the National Natural Science Foundation of China(No.62304070).