摘要
氧化反应单原子催化剂催化是有机反应的主要应用领域之一,其中有氧氧化和类芬顿反应占据重要地位。阐明单原子催化机理是优化催化剂设计与性能的关键。结合近年来发表的单原子催化剂催化氧化反应的实例,综述了单原子催化体系中有氧氧化反应和类芬顿反应的一般规律,对未来催化氧化反应的单原子催化剂理性调控提供了借鉴意义。
Oxidation reactions represent one of the primary application fields of single-atom catalysts in organic transformations,among which aerobic oxidation and Fenton-like reactions play pivotal roles.A systematic understanding of the mechanisms by which SACs function in these two types of reactions is fundamental to the development of innovative SACs and the enhancement of catalytic oxidation efficiency.This review consolidates the general principles governing aerobic oxidation and Fenton-like reactions in single-atom catalytic systems by analyzing recent examples of SAC-mediated oxidation reactions.Furthermore,it provides insights into the future design and preparation of SACs for catalytic oxidation applications.
作者
王友志
WANG Youzhi(College of Chemistry&Chemical Engineering,Northeast Petroleum University,Daqing 163318,China)
出处
《化工科技》
2025年第4期74-78,共5页
Science & Technology in Chemical Industry
基金
中国博士后基金面上资助项目(2019M661247)
中国博士后基金特别资助项目(2020T130091)
黑龙江省自然科学基金优秀青年项目(YQ2022B002)。
关键词
有氧氧化
类芬顿
单原子催化剂
Aerobic oxidation
Fenton-like
Single-atom catalyst
