摘要
The degradation of Lithium-ion batteries(LIBs)during cycling is particularly exacerbated at low temperatures,which has a significant impact on the longevity of electric vehicles,energy storage systems,and consumer electronics.A comprehensive understanding of the low-temperature aging mechanisms throughout the whole life cycle of LIBs is crucial.However,existing research is limited,which typically focuses on capacity degradation to 80%.To fill this gap,this paper conducts low-temperature cyclic aging tests at three different charging rates.The investigation employs differential voltage analysis,the distribution of relaxation times technique,and disassembly characterization to explore both thermodynamic degradation and kinetic degradation,alongside a correlation analysis of the factors influencing these degradation processes.The results reveal two distinct knee points in the capacity decline of LIBs during the whole life cycle,in contrast to prior studies identifying only one.Before the first knee point,the thickening of the SEI film dominates capacity loss,with higher charging rates accelerating the process.After the first knee point,the main degradation mechanisms shift to lithium plating and the fracture of the positive electrode active particles.These two aging factors become more pronounced with ongoing cycling,culminating in a second knee point in capacity decline.Notably,a novel finding demonstrates that after the second knee point,capacity degradation progresses faster at lower charging rates compared to medium rates.The reason is the fracture of graphite particles also becomes a critical contributor to the severe capacity degradation at lower charging rates.These insights will guide the designs of next-generation low-temperature LIBs and low-temperature battery management systems.
基金
financially supported by the National Natural Science Foundation of China(NSFC,Grant number U20A20310)
the Program of Shanghai Academic/Technology Research Leader(Grant number 22XD1423800)。
