摘要
The utilization of Li-rich layered oxides(LLOs)as cathodes in high-energy Li-ion batteries is significantly hindered by serious voltage decay and capacity fading due to irreversible oxygen release and transition metal(TM)migration triggered by the lattice strain.Herein,B ions are effectively incorporated into the tetrahedral vacancies situated between TM slab and Li layer of LLOs.The robust B-O bond,along with the low Bader charge of oxygen within BO_(4) tetrahedra,alleviates excessive oxidation of O anions while substantially reinforcing the oxygen framework.Consequently,the B-doped LLO sample exhibits only slight variation in lattice parameters,especially the c-axis,which can be characterized as exhibiting“zero-strain”as supported by in situ XRD data.As a result,the discharge capacity of the B-LLO sample maintains 210.66 mAh·g^(−1) after 300 cycles,with a retention ratio of 90.7%.
基金
supported by the Applied Basic Research Fund of Guangdong Province(No.2024B1515020071)
the National Natural Science Foundation of China(Nos.52371217 and 52150410411)
the Science and Technology Innovation Plan Project of Hunan Province(No.2024RC3217)
Guangdong Provincial Science and Technology Plan Project(No.2023A0505020009).
