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Cu/Fe/Mo/Nb改性HZSM-5催化乙醇胺富液解吸CO_(2)的性能研究

Study on the Performance of Cu/Fe/Mo/Nb Modified HZSM-5 Catalyst for Desorption of CO_(2)from Ethanolamine Enrichment Solution
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摘要 采用等体积浸渍法在HZSM-5负载不同含量的Cu、Fe、Mo和Nb,在98℃油浴下研究金属改性HZSM-5对5 mol/L乙醇胺(Monoethanolamine,MEA)富液解吸CO_(2)的影响,并与空白对照实验进行对比。结果表明,0.6Nb-HZSM-5催化效果最佳,可将最大解吸速率提高74.6%,解吸负载提高46.3%,相对能耗降至65.2%;0.6Nb-HZSM-5经4次使用后可将解吸负载提升40.0%,相对能耗降低30.5%,具有良好的稳定性,成型后催化效果优于HZSM-5。 The equal volume impregnation method was adopted to load different contents of Cu,Fe,Mo and Nb on HZSM-5.The effect of metal-modified HZSM-5 on the desorption of CO_(2)in 5 mol/L monoethanolamine(MEA)rich liquid was studied under an oil bath at 98℃,and it was compared with the blank control experiment.The results show that 0.6Nb-HZSM-5 has the best catalytic effect,which can increase the maximum desorption rate by 74.6%,increase the desorption load by 46.3%,and reduce the relative energy consumption to 65.2%;After four uses,0.6Nb-HZSM-5 can increase the desorption load by 40.0%and reduce the relative energy consumption by 30.5%.It has good stability and the catalytic effect after molding is better than that of HZSM-5.
作者 吴亚杰 曹蒙欢 何昭卫 王建华 苟湘 Wu Yajie;Cao Menghuan;He Zhaowei;Wang Jianhua;Gou Xiang(School of Energy and Environmental Engineering,Hebei University of Technology,Tianjin,300401)
出处 《当代化工研究》 2025年第11期1-4,共4页 Modern Chemical Research
关键词 金属改性HZSM-5 CO_(2)解吸 能耗 酸性位点 metal-modified HZSM-5 CO_(2)desorption energy consumption acidic site
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