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Exploring temperature-driven phase dynamics of phosphate:The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO_(4)

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摘要 The study of temperature-driven phase transitions is significant in phosphate chemistry,as these transitions often lead to unique physical properties for specific applications,such as catalysis,energy storage,ion conduction,and nonlinear optics[1–3].The phase transition from room temperature(RT)to high temperature(HT)in phosphates is always from periodic structures to disordered or amorphous states[4–8].At RT,phosphates often maintain a highly ordered crystalline structure,which is stabilized by the lower thermal energy.As the temperature increases,the thermal energy disrupts the periodic arrangement of atoms and leads to a phase transition,where the once ordered structure becomes increasingly disordered or even amorphous.
出处 《Chinese Journal of Structural Chemistry》 2025年第1期18-20,共3页 结构化学(英文)
基金 supported by the National Natural Science Foundation of China(22105218) Science and Technology Project of Jiangxi Provincial Education Department(GJJ2201525).
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