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What drives the heterogeneous interdiffusion in the Li-Si interfacial region of Si anodes:the Li flux or the Si flux?

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摘要 The electrochemical reaction in silicon(Si)electrode,accompanying with tremendous volume expansion,causes rapid capacity fade of Li-ion batteries.The Li-ion concentration gradient and structural distribution uniformity influence the inhomogeneous expansion,and the kinetic mechanism of lithiation and interfacial morphology evolvement remains debated.
出处 《npj Computational Materials》 CSCD 2024年第1期1919-1927,共9页 计算材料学(英文)
基金 funding support from the Ministry of Science and Technology of People’s Republic of China(Grant No.2021YFB3800303) DP Technology Corporation(Grant No.2021110016001141) the National Natural Science Foundation of China(Grants No.22008096).
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