摘要
The electrochemical reaction in silicon(Si)electrode,accompanying with tremendous volume expansion,causes rapid capacity fade of Li-ion batteries.The Li-ion concentration gradient and structural distribution uniformity influence the inhomogeneous expansion,and the kinetic mechanism of lithiation and interfacial morphology evolvement remains debated.
基金
funding support from the Ministry of Science and Technology of People’s Republic of China(Grant No.2021YFB3800303)
DP Technology Corporation(Grant No.2021110016001141)
the National Natural Science Foundation of China(Grants No.22008096).