摘要
In the photothermal synergistic catalytic conversion of CO_(2)and H_(2)O,the catalyst harnesses solar energy to accumulate heat,thereby elevating the reaction system’s temperature.The influence of this temperature effect on surface chemical reactions remains an underexplored area.Here the impact of temperature on the surface-level thermodynamic reactions and conversion of CO_(2)with H_(2)O on oxide semiconductors at the atomic scale was investigated using first-principle calculations.
基金
supported by the National Natural Science Foundation of China(52341602)
Zhejiang Provincial Natural Science Foundation of China under Grant No.LDT23E06014E06
Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ24E060001
National Key Research and Development Project(2023YFC3710800)
Fundamental Research Funds for the Central Universities(2022ZFJH004)
funded by the China Scholarship Council.
