摘要
本文综述了金属有机框架(MOFs)基催化剂用于光催化合成过氧化氢的发展现状,从催化剂的设计合成角度总结了当前MOFs基光催化剂的设计策略(多元杂化策略、金属团簇设计改进策略、连接剂缺陷工程、双连接剂及配体功能化策略和疏水化策略),概述了光催化合成过氧化氢在不同领域的应用,并对光催化合成过氧化氢的MOFs催化剂的未来发展进行了展望.
Hydrogen peroxide(H_(2)O_(2))is an environmentally friendly oxidizing agent,which is widely used in various fields.For a long time,anthraquinone(AQ)method has been the main process for industrial production of H_(2)O_(2)because of its high degree of automation and suitability for large-scale production.However,the traditional AQ process is complicated,high energyintensive,more toxic by-products,and not suitable for the production needs of the present era.In addition to the AQ process,there are many other routes for H_(2)O_(2)generation,but for various reasons they have been eliminated.Photocatalysis is considered to be a greener and more environmental production path,so photocatalytic synthesis of H_(2)O_(2)has aroused great interest.The H_(2)O_(2)production by photocatalysis is based on the abundant water and O2 on the earth,renewable sunlight as energy supply,semiconductors as photocatalysts,and the cost is relatively low,and the reaction conditions are mild.Therefore,the photocatalytic production of H_(2)O_(2)has broad application prospects,and it stands out among many methods for preparing H_(2)O_(2).Among the many photocatalysts that have been reported,there are common defects of poor light absorption performance,poor stability and non-recyclability,which greatly limit their application in H_(2)O_(2)production.Metal-organic frameworks(MOFs)have been widely used in the field of photocatalysis due to their rich pores,high specific surface area,good chemical stability,customizable and diverse structures,and easy modification of organic linkers and clusters.In this review,the basic principle of light-driven H_(2)O_(2)generation is introduced,and the development status of MOFs-based catalyst for photocatalytic H_(2)O_(2) generation is emphasized.In particular,the synthesis strategy of the photocatalyst is summarized in the aspects of multicomponent hybridization,metal-oxygen cluster design,ligand defect engineering,ligand functionalization and hydrophobicity in detail.In addition,this review looks forward to the development trend of the design and synthesis of MOFs-based photocatalysts for H_(2)O_(2)generation.
作者
夏志楠
吕长利
XIA Zhi-nan;LYU Chang-li(Faculty of Chemistry,Northeast Normal University,Changchun 130024,China)
出处
《分子科学学报》
CAS
北大核心
2023年第5期377-391,共15页
Journal of Molecular Science
基金
吉林省自然科学基金资助项目(20210101404JC).
关键词
金属有机骨架
过氧化氢
光催化
光催化剂设计
metal-organic frameworks
hydrogen peroxide
photocatalysis
photocatalyst design
