摘要
Porous polymer(pyrrolopyrrole)was successfully prepared via domino-ring-formation reaction.The chemical-physical properties of cyanided covalent triazine frameworks(CTF-CN)were characteriazed by fourier transform infrared spectra(FT-IR),scanning electron microscopy(SEM),nuclear magnetic resonance(NMR),specific surface area analyzer(BET)and thermogravimetric analysis(TGA),respectively.The experimental results of adsorption of chloranil(TCBQ)in aqueous solution indicated that CTF-CN exhibited distinctive adsorption capacity toward TCBQ owing to its large specific surface area.Specifically,the adsorption equilibrium of as-prepared polymer was executed within 5 h and the calculated adsorption capacity was 499.76 mg/g.Furthermore,the adsorption kinetics could be well defined with the linear pseudo-second-order model,which implies that the chemical interaction are relative important in the course of TCBQ removal.Finally,the current studies verify that CTF-CN has unique rigid and nano-porous framework structure,which can be employed for the treatment of a series of harmful aromatic substances.
作者
金英伟
XIE Peidong
YANG Yuying
RONG Gaoqi
LI Pingdeng
HU Yeli
CHENG Bo
ZHENG Qi
汪畅
JIN Yingwei;XIE Peidong;YANG Yuying;RONG Gaogi;LI Pingdeng;HU Ye;CHENG Bo;ZHENG Qi;WANG Chang(Hubei Key Laboratory of Environmental and Health Effects of Persistent Toxic Substances,Institute of Environment and Health,Jianghan University,Wuhan 430056,China;School of Environmental Ecology and Biological Engineering,Wuhan Institute of Technology,Wuhan 430025,China;School of Chemistry and Chemical Engineering,Wuhan University of Science and Technology,Wuhan 430081,China;Key Laboratory of Optoelectronic Chemical Materials and Devices,Jianghan University,Wuhan 430056,China)
基金
the National Natural Science Foundation of China(Nos.21976069,21677062,21507155)。
