摘要
目的 综述了环保增塑剂制备的新方法与应用研究,为环保型增塑剂在聚氯乙烯中的应用提供一定的理论依据。方法 根据环保型增塑剂化学结构和功能的不同对其进行了分类,重点介绍国内外环保增塑剂的最新研究进展,详细介绍环氧植物油类、聚酯类、柠檬酸酯类、偏苯三酸酯类、环己烷二羧酸酯类等环保型增塑剂在聚氯乙烯中的应用研究,指出环保增塑剂需要解决的主要问题,并以此为基础对环保型增塑剂在聚氯乙烯中的发展趋势进行展望。结果 环保型增塑剂增塑改性的聚氯乙烯在力学性能、耐热性能、加工性能和稳定性等方面都媲美或优于邻苯二甲酸酯类增塑剂。结论 环保型增塑剂可替代具有潜在危害的邻苯二甲酸酯类增塑剂,具有广阔的应用前景。
The work aims to summarize new preparation methods and application of environmentally-friendly plasticizers to provide certain theoretical basis for the application of environmentally-friendly plasticizers in polyvinyl chloride.Different types of environmentally-friendly plasticizers were classified according to their chemical structure and function.The latest research of environmentally-friendly plasticizers at home and abroad was mainly introduced. Besides, the application of several environmentally-friendly plasticizers in PVC was introduced in detail, including epoxidized plasticizer, polyester plasticizer, citric acid ester plasticizers, trimellitic ester plasticizers, and cyclohexane dicarboxylic acid ester plasticizer. The main problems that need to be solved for environmentally-friendly plasticizers were revealed. On this basis, the development direction and industrial prospect of environmentally-friendly plasticizers were analyzed and predicted. Moreover, the findings suggested that polyvinyl chloride modified by environmentally-friendly plasticizers was comparable or superior to phthalate plasticizer in mechanical properties, heat resistance, processing performance and stability. Potentially harmful phthalate plasticizers can be replaced by environmentally-friendly plasticizers, which have great application prospects in polyvinyl chloride.
作者
吴海龙
农桂叶
曹宇
钟山
王海明
WU Hai-long;NONG Gui-ye;CAO Yu;ZHONG Shan;WANG Hai-ming(School of Data Science and Software Engineering,Wu Zhou University,Guangxi Wuzhou 543002,China;School of Mechanical and Resource Engineering,Wu Zhou University,Guangxi Wuzhou 543002,China;Guangxi Key Laboratory of Machine Vision and Intelligent Control,Wuzhou University,Guangxi Wuzhou 543002,China;College of Innovation and Entrepreneurship,Hunan Railway Professional Technology College,Hunan Zhuzhou 412001,China)
出处
《包装工程》
CAS
北大核心
2022年第7期118-124,共7页
Packaging Engineering
基金
2020年梧州高新区、梧州学院产学研项目(2020G006)
2021年度广西高校中青年教师科研基础能力提升项目(2021KY0678)
湖南省科学技术厅2019年大学生科技创新创业能力培养项目(湘科人[2019]8号)
湖南省科学技术厅2020年湖南省众创空间(湘科计[2020]64号)。
关键词
环保型增塑剂
聚氯乙烯
应用
展望
environmentally-friendly plasticizer
polyvinyl chloride
application
prospect
