摘要
氮化铁具有硬度高、熔点高、热导性高、耐腐蚀、安全无污染、电子导电性优异以及类铂的电子结构等优势,且其原材料资源丰富、成本低廉,在储能与电催化等众多领域中有着极大的应用前景。本文综述了铁基氮化物在结构、制备、性能和应用方面的研究进展,重点关注其制备方法和在储能领域(如锂离子电池、钠离子电池、锂硫电池)、电催化领域(如氢析出反应、氧析出反应、氧还原反应)中的应用,同时对铁基氮化物存在的主要问题进行了总结,对其未来的研究方向和应用前景进行了展望。
Iron nitrides feature in high hardness, high melting point, high thermal conductivity, corrosion resistance, safety and pollution-free, excellent electronic conductivity, as well as platinum-like electronic structure. The abundant raw material resources and low cost facilitate iron nitrides show great prospects in many fields, such as energy storage and electrocatalysis applications. This review summarizes the recent research progress of iron-based nitrides in terms of the structure, synthesis methods, electrochemical performance and applications. The advances in the field of energy storage(such as lithium-ion batteries, sodium-ion batteries, lithium-sulfur batteries) and electrocatalysis(such as hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction) are discussed in detail. Meanwhile, the challenges and future perspective targeting energy related applications of iron-based nitrides are outlined.
作者
黄强
孙兵
徐文莉
丛野
陈永婷
朱辉
李轩科
张琴
HUANG Qiang;SUN Bing;XU Wenli;CONG Ye;CHEN Yongting;ZHU Hui;LI Xuanke;ZHANG Qin(Hubei Coal Conversion and New Carbon Materials Key Laboratory,Wuhan University of Science and Technology,Wuhan 430081,China)
出处
《人工晶体学报》
CAS
北大核心
2022年第2期344-359,共16页
Journal of Synthetic Crystals
基金
国家自然科学基金青年项目(51902232)。
关键词
铁基氮化物
复合材料
制备
储能
电催化
应用
iron-based nitride
composite
synthesis
energy storage
electrocatalysis
application
