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基于悬浮聚合法的含能中空微囊制备

Preparation of Energetic Hollow Microcapsules Using Suspension Polymerization Method
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摘要 针对传统乳化炸药加入含能添加剂后存在的相容性和安全性问题,分别采用固体膨胀剂法和液体膨胀剂法研制了一种含能中空微囊,并对其物理性能进行了表征。结果表明:采用固体膨胀剂法和液体膨胀剂法合成的含能微囊均具有较好的表面形貌和中空结构,其平均粒径分别为107.0μm和58.5μm;与4-4-氧代双苯磺酰肼相比,偶氮二甲酰胺更适合用作微囊的固体膨胀剂;液体膨胀剂制备含能中空微囊时,利用高低压差发泡的微囊具有更好的膨胀效果。 Aimed at the compatibility and safety problem of energetic additives in the traditional emulsion explosives,energetic hollow microcapsules were prepared by solid swelling agent and liquid swelling agent,and the physical properties of the energetic hollow microcapsules were characterized.The results show that the energetic microcapsules prepared by the solid swelling agent and liquid swelling agent have good morphologies and hollow structures without agglomeration,the average particle size is 107.0μm and 58.5μm,respectively.The Ac agent is more suitable to be used as the solid swelling agent compared to the OBSH agent,the pressure difference foaming method has better expansion effect for the liquid swelling method.
作者 高朋飞 汪旭光 姚雨乐 夏煜 宗琦 程扬帆 GAO Peng-fei;WANG Xu-guang;YAO Yu-le;XIA Yu;ZONG Qi;CHENG Yang-fan(School of Civil Engineering and Architecture,Anhui University of Science and Technology,Huainan,232001;Anhui Engineering Laboratory of Explosive Materials and Technology,Huainan,232001)
出处 《火工品》 CAS CSCD 北大核心 2022年第1期72-75,共4页 Initiators & Pyrotechnics
基金 国家自然科学基金面上项目(11972046) 安徽理工大学创新基金项目(2020CX2066)。
关键词 乳化炸药 含能添加剂 微胶囊 膨胀剂 物理性能 Emulsion explosive Energetic additives Microcapsule Swelling agent Physical performance
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