期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

High-efficiency separation and extraction of naphthenic acid from high acid oils using imidazolium carbonate ionic liquids 被引量：1

在线阅读 下载PDF
导出
摘要 N-alkyl imidazolium carbonate ionic liquids were employed to separate and recover naphthenic acid from model oils.The effects of the cationic and anionic structures of ionic liquids and operating conditions on the deacidification performance were investigated.The deacidification performance of traditional organic solvents was also investigated for comparison.The results indicated that the naphthenic acid could be completely removed from the model oil with a small mass ratio of ionic liquid to oil.The extracted naphthenic acid was regenerated with a recovery of up to 92%.In addition,imidazolium carbonate ionic liquids could be successfully regenerated and recycled.The mechanism of interaction between imidazole ionic liquids and the naphthenic acid molecules were explained by Gauss calculation.
作者 Fenghua Geng Rui Zhang Luo Wu Zheng Tang Han Liu Haiyan Liu Zhichang Liu Chunming Xu Xianghai Meng
机构地区 State Key Laboratory of Heavy Oil Processing
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第1期252-259,共8页 中国化学工程学报（英文版）
基金 support of the National Natural Science Foundation of China(22078359,21276275).
关键词 EXTRACTION Ionic liquid Naphthenic acid Recovery Computational chemistry
分类号 TQ028 [化学工程] TQ235 [化学工程—有机化工] O645.1 [理学—物理化学]
  • 相关文献

参考文献2

二级参考文献103

  • 1HUDDLESTON J G, WILLAUER H D, SWATLOSKI R P, et al. Room temperature ionic liquids as novel media for ‘Clean' liquid-liquid extraction[J]. Chemical Communications, 1998, 16: 1765-1766.
  • 2LARRIBA M, NAVARRO P, GARCIA J, et al. Liquid-liquidextraction of BTEX from reformer gasoline using binary mixtures of [4empy][Tf2N] and [Emim] [DCA] ionic liquids[J]. Energy & Fuels, 2014, 28 (10): 6666-6676.
  • 3DOMrNGUEZ I, GONZALEZ E J, DOMiNGUEZ A. Liquid extraction of aromatic/cyclic aliphatic hydrocarbon mixtures using ionic liquids as solvent: literature review and new experimental LLE data[J]. Fuel ProcessingTechnology, 2014, 125: 207-216.
  • 4LARRIBA M, NAVARRO P, GARC[A J, et al. Separation of toluene from n-heptane, 2,3-dimethylpentane, and cyclohexane using binary mixtures of [4empy][Tf2N] and [Emim][DCA] ionic liquids as extraction solvents[J]. Separation and Purification Technology, 2013, 120: 392-401.
  • 5JACQUEM1N J, ZHENGY, WANGY, et al. Proceedings of the 4th international gas processing symposium[C]. Oxford: Elsevier, 2015: 243-250.
  • 6ARCE A, EARLE M J, RODILIGUEZ H, et al. Separation of benzene and hexane by solvent extraction with 1 -alkyl-3 -methylimidazolium bis {(trifluoromethyl)sulfonyl} amide ionic liquids: effect of the alkyl-substituent length[J]. Journal of Physical Chemistry B, 2007, 111 ( 18): 4732-4736.
  • 7ARCE A, EARLE M J, RODRIGUEZ H, et al. Separation of aromatic hydrocarbons from alkanes using the ionic liquid 1-ethyl-3-methylimidazoliumbis {(trifluoromethyl) sulfonyl} amide [J]. Green Chemistry, 2007, 9 (1): 70-74.
  • 8LARRIBA M, NAVARRO P, GARdA J, et al. Liquid-liquid extraction of toluene from heptane using [Emim][DCA] , [Bmim][DCA], and [Emim][T[M] ionic liquids[J]. Industrial & Engineering Chemistry Research, 2013, 52 (7): 2714-2720.
  • 9CORDERJ S, CALVAR N, GOMEZ E, et al. Quaternary (liquid+liquid) equilibrium data for the extraction of toluene from alkanes using the ionic liquid [Emim][MSO4][J]. The Journal of Chemical Thermodynamics, 2014, 76: 79-86.
  • 10MANOHAR C V, BANERJEE T, MOHANTY K. Co-solvent effects for aromatic extraction with ionic liquids[j]. Journal of MolecularLiquids, 2013, 180: 145-153.

共引文献22

同被引文献10

引证文献1

二级引证文献2

Chinese Journal of Chemical Engineering
2022年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部