摘要
以邻溴硝基苯为起始原料,经Suzuki偶联反应、Cadogan关环反应、Ullmam反应、Buchwald反应等合成了目标产物N-(9,9-二苯基-9 H-芴-2-基)-N,9-二苯基-9 H-咔唑-2-胺,其结构经^(1)H NMR、^(13)C NMR和HR-MS(ESI)确证,并采用TG-DSC、UV-Vis对产物的热稳定性能和光学性能进行了研究。
The target compound N-(9,9-diphenyl-9 H-fluoren-2-yl)-N,9-diphenyl-9 H-carbazole-2-amine was synthesized by Suzuki coupling reaction,Cadogan ring closing reaction,Ullmam reaction and Buchwald reaction,with o-bromonitrobenzene as the starting material.The structure was confirmed by ^(1)H NMR,^(13)C NMR,HR-MS(ESI).And the thermal stability and optical property of the target product were studied by TG-DSC and UV-Vis.
作者
陈鹏丽
刘畅
李瑞
黄歆童
杨振强
CHEN Peng-li;LIU Chang;LI Rui;HUANG Xin-tong;YANG Zhen-qiang(Henan Academy of Sciences Institute of Chemistry Co.,Ltd.,Zhengzhou 450002,China;Henan Chuangan Optoelectronics Technology Co.,Ltd.,Zhengzhou 450002,China)
出处
《合成化学》
CAS
2021年第10期867-871,共5页
Chinese Journal of Synthetic Chemistry
基金
河南省科学院科研开发专项(200603059)
河南省科学院人才队伍建设专项(200503001)
河南省科学院重大科研聚焦项目(210103001)。
