摘要
铝土矿是化学风化作用的细粒终极产物,与强烈的化学风化作用密切相关。根据母岩的类别及作用过程,风化作用进一步分为铝硅酸盐岩强化学风化形成的红土化作用和碳酸盐岩强化学风化形成的钙红土化作用。在强烈的化学风化过程中,地表的原始沉积物(母岩)的原生矿物发生溶蚀、水解、水化、碳酸化、氧化,破坏原始的矿物结构,形成新的细粒矿物(主要是黏土质矿物)。在适合的地质条件下,持续的强烈化学风化作用会造成大部分活动的元素(如K、Na、Ca、Mg、Si)的流失与Al的残留富集从而形成铝土矿。现在观察到的沉积型铝土矿,虽然与古风化壳具有密切联系,但沉积型铝土矿多数是由沉积过程搬运到沉积盆地中所形成的强化学风化产物的沉积层,与古风化壳的残坡积层具有显著差别,只有少数工业价值不大(品位低、品质差)的残坡积相铝土矿。铝土矿含矿岩系的沉积环境与铝土矿(尤其是高品位、高品质的铝土矿)的成矿环境不尽相同。铝土矿主要形成于暴露于大气中的陆表环境(而非水下环境),由地下水淋滤作用形成(在渗流带由活动元素流失、Al等稳定元素残留富集而成)。本研究在铝土矿成矿作用分析等基础上,提出了以铝土矿沉积物等物源和沉积、成矿作用为依据的中国铝土矿床分类方案,包括原地或准原地残坡积物成因的红土型和喀斯特型,和异地物源沉积成因的沉积型。
Bauxite is the ultimate fine-grained products of chemical weathering,and thus it is closely linked with the intense chemical weathering.Based on variations of parent rock and weathering processes,the weathering products can be subdivided into laterite and terra rossa,of which the former is formed by weathering of aluminosilicates and the latter is produced by the weathering of carbonates.During the intense chemical weathering,minerals in original subaerial sediments(parent rocks)would suffer a series of processes(dissolution,hydrolyzation,hydration,carbonation,and oxidation)and be destroyed or transformed,leading to formation of new minerals.In the favorable environment,continuously intense chemical weathering would cause the loss of most mobile elements(e.g.,K,Na,Ca,Mg,Si)and the enrichment of Al,resulting in the formation of bauxite.Although sedimentary bauxites are closely linked with the weathering curst,they show obvious differences in formation processes.Sedimentary bauxites are composed of intense chemical weathering products that are transported from outside of the basin and re-deposited in the basin,while most weathering crusts are transformed from saprolite and/or deluvium in-situ,and they can only form low-grade bauxites.Sedimentary environments also differ in bauxite ore layers and bauxitic claystone layers.Bauxite ore layers are formed in the subaerial environment and controlled by the leaching process of groundwater in the vadose zone.Based on the analysis of bauxitization,this study proposes to use multiple parameters,such as provenance,sedimentation and mineralization,to build the new classification of Chinese bauxite deposits.In this classification,lateritic and karstic types of bauxite deposits are autochthonous or parautochthonous saprolite and/or deluvium,while sedimentary type is dominated by heterochthonous provenance.
作者
杜远生
余文超
Du Yuan-Sheng;Yu Wen-Chao(State Key Laboratory of Biogeology and Environmental Geology,School of Earth Sciences,China University of Geosciences(Wuhan),Wuhan 430074,China;Innovation Center of Ore Resources Exploration Technology in the Region of Bedrock,Ministry of Natural Resources of People's Republic of China,Guiyang 550081,China)
出处
《古地理学报》
CAS
CSCD
北大核心
2020年第5期812-826,共15页
Journal of Palaeogeography：Chinese Edition
基金
国家自然科学基金项目(编号:U1812402,41802116)
中国地质大学(武汉)中央高校基金项目(编号:CUG170684,CUGQY1908)联合资助。
关键词
陆表淋滤成矿
沉积型铝土矿
风化壳
铝土矿分类
subaerial leaching
sedimentary bauxites
weathering crust
bauxite classification
