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BiVO4/TiO2广谱光催化剂的合成及光催化性能

Synthesis of Broad-spectrum Photocatalyst BiVO4/TiO2 and Its Photocatalytic Property
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摘要 用低温溶胶-凝胶法,合成了BiVO4/TiO2系列复合光催化剂。采用X射线衍射、比表面积、紫外-可见漫反射光谱和荧光发射光谱对样品进行表征,用模拟太阳光降解亚甲基蓝评价复合光催化剂的催化活性。结果表明:复合光催化剂在480-800nm的可见光范围具有较强的吸收峰,当BiVO4的质量分数为30%时,呈现出最好的光谱吸收性能;BiVO4与TiO2之间形成的异质结,能快速捕获并迁移电子,有效地提高光生电子-空穴的分离效率,从而提高其光催化活性。 BiVO4/TiO2 series composite photocatalysts were synthesized by low temperature sol-gel method.The samples were characterized by X-ray diffraction,scanning electron microscope,specific surface area,UV-Vis techniques and photoluminescence spectra.The photocatalytic activity was evaluated by degradation of methylene blue under simulated sunlight irradiation.It was found that the composite photocatalysts have a strong absorption peak in the 480-800 nm range of visible light.When the mass fraction of BiVO4 was 30%,it showed the best spectral absorption performance.The formation of heterojunction between BiVO4 and TiO2 can capture and transfer the photogenerated charges,leading to an efficient improvement in photocatalytic activity.
作者 王美 李文军 Wang Mei;Li Wenjun(Huaibei Normal University,Huaibei 235000,China;University of Science and Technology Beijing,Beijing 100083,China)
出处 《廊坊师范学院学报(自然科学版)》 2020年第3期41-46,共6页 Journal of Langfang Normal University(Natural Science Edition)
基金 安徽省教学研究一般项目(2019szjy174)。
关键词 BiVO4/TiO2 广谱 溶胶-凝胶法 光催化 BiVO4/TiO2 broad spectrum sol-gel method photocatalytic
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  • 1王智宇,唐培松,蒋玉龙,樊先平,钱国栋,洪樟连.量子尺寸纳米TiO2的荧光及漫反射光谱[J].稀有金属材料与工程,2004,33(z1):162-165. 被引量:13
  • 2高善民,乔青安,赵培培,陶芙蓉,张江,戴瑛,黄柏标.沉淀法制备不同形貌和结构的纳米BiVO_4[J].无机化学学报,2007,23(7):1153-1158. 被引量:25
  • 3Zhou K F,Zhu Y H,Yang X L,et al.Preparation of grapheneTi O2composites with enhanced photocatalytic activity.New J Chem,2011,35(2):353.
  • 4Zhang A P,Zhang J Z.Characterization and photocatalytic properties of Au/Bi VO4composites.J Alloys Compd,2010,491(1--2):631.
  • 5Yan Y,Sun S F,Song Y,et al.Microwave-assisted in situ synthesis of reduced graphene oxide-Bi VO4composite photocatalysts and their enhanced photocatalytic performance for the degradation of ciprofloxacin.J Hazard Mater,2013,250-251:106.
  • 6Hu Y,Li D Z,Zheng Y,et al.Bi VO4/Ti O2nanocrystalline heterostructure:a wide spectrum responsive photocatalyst towards the highly efficient decomposition of gaseous benzene.Appl Catal B,2011,104(1-2):30.
  • 7Cao B W,Peng J H,Xu Y H.Simulated sunlight-driven degradation of Rhodamine B by porous peanut-like Ti O2/Bi VO4composite.J Cluster Sci,2013,24(3):771.
  • 8Du A J,Ng Y H,Bell N J,et al.Hybrid graphene/titania nanocomposite:interface charge transfer,hole doping,and sensitization for visible light response.J Phys Chem Lett,2011,2(8):894.
  • 9Zhang Y H,Zhang N,Tang Z R,et al.Graphene transforms wide band gap Zn S to a visible light photocatalyst:the new role of graphene as a macromolecular photosensitizer.ACS Nano,2012,6(11):9777.
  • 10Wang J X,Wang P X,Cao Y T,et al.A high efficient photocatalyst Ag3VO4/Ti O2/graphene nanocomposite with wide spectral response.Appl Catal B,2013,136-137:94.

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