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钴(Ⅲ)咔咯合成与应用研究进展

Research Progress on the Synthesis and Application of Co(Ⅲ) Corroles
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摘要 综述了不同类型咔咯自由碱及其金属钴(Ⅲ)配合物的合成方法,并分类探讨了不同类型的金属钴(Ⅲ)咔咯在能源化学与环境化学领域的应用,包括(1)电化学催化氧气还原;(2)分子传感器;(3)有机氯污染物降解;(4)烯烃催化氧化。同时,对钴(Ⅲ)咔咯化学未来的发展方向进行了展望。 Herein, we have summarized the recent progress on the synthesis of free base corroles and their Co(Ⅲ)corroles, and the applications in different fields including:(1)electrochemically catalyzed oxygen reductions;(2)molecular sensors;(3)degradation of environmentally toxic organochlorides;(4)catalytic oxidation of olefins. The future prospect of the synthesis and applications of Co(Ⅲ)corroles were also described.
作者 张振 张奎 朱卫华 梁旭 ZHANG Zhen;ZHANG Kui;ZHU Wei-hua;LIANG Xu(Suqian Health College,Suqian 223800,China;School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,China)
出处 《合成化学》 CAS 北大核心 2020年第3期250-255,共6页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(21701058) 江苏省自然科学基金资助项目(BK20160499) 配位化学国家重点实验室开放基金资助项目(SKLCC1817) 功能无机材料化学教育部重点实验室开放基金资助项目 中国博士后基金资助项目(2018M642183) 兰州市创业创新人才基金资助项目(2018-RC-105) 江苏大学高级人才基金资助项目(17JDG035)。
关键词 钴咔咯 合成 催化化学 能源化学 环境化学 综述 Co(Ⅲ)corrole synthetic method catalysis energy chemistry environment chemistry review
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