摘要
光合作用是大自然中最重要的合成反应,其产氧中心包括关键的锰-氧-钙结构单元。锰元素在地壳中储量大、毒性低、氧化态丰富,具有独特的反应性,因此,人工利用锰元素实现自然界不能实现的物质合成具有重要的意义和广阔的前景。本文简述了锰元素促进的合成化学的发展历史,及其近年来在无机电化学、有机合成等领域中的应用。
Photosynthesis is the most important synthetic reaction in nature, the O2-evolution center of which contains the key Mn-O-Ca structure motif. Manganese features earth abundance, low toxicity, rich oxidative states, and unique reactivities, which makes it of great importance and hold huge potentials to achieve new synthesis unavailable by nature. In this paper, the history of manganese-enabled synthetic chemistry and its recent applications in inorganic electrochemistry and organic synthesis are reviewed briefly.
作者
于夕雯
杨芸辉
王从洋
YU Xiwen;YANG Yunhui;WANG Congyang(Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory of Molecular Recognition and Function,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,P.R.China;University of Chinese Academy of Sciences,Beijing 100049,P.R.China;Physical Science Laboratory,Huairou National Comprehensive Science Center,Beijing 101400,P.R.China)
出处
《大学化学》
CAS
2019年第12期64-72,共9页
University Chemistry
基金
国家自然科学基金(21772202,21831008)
北京分子科学国家研究中心(BNLMS-CXXM-201901)
北京怀柔综合性国家科学中心物质科学实验室(Z181100004218004)
关键词
锰
锰氧化物
羰基锰化合物
合成化学
Manganese
Manganese oxides
Manganese carbonyl complexes
Synthetic chemistry
