摘要
The complexes RE_2(DHYA)_3 centre dot nH_2O in the title bar were synthesizedthrough some reactions of trivalent rare-earth ions. In the process of synthesis, dihydroxamicacids were taken as ligands while the alcohol was taken as a solvent. The ligands includedadipylhydroxamic acid (ADHA), p-phthalichydroxamic acid (PPHA), oxalohydroxamic acid (OXHA),butadihydroxamic acid (BDHA), o-phthalichydroxamic acid (OPHA), benzoylhydroxamic acid (BHA), etc.Measured at 25 deg C, the molar conductances in various modes are 13.00-21.05 S centre dot cm^2centre dot mol^(-1), which shows that rare-earth complexes are nonelectrolytes and the hydroxaminogroups of the complexes have taken part in bonding. Infrared spectra, ultraviolet spectra, nuclearmagnetic resonance (~1HNMR) spectra, and fluorescence spectra were used to investigate thecomplexes. Experiments have proved that the complexes of En^(3+)and Tb^(3+) with aromatic hydroxamicacids have good fluorescent characteristics.
The complexes RE_2(DHYA)_3 centre dot nH_2O in the title bar were synthesizedthrough some reactions of trivalent rare-earth ions. In the process of synthesis, dihydroxamicacids were taken as ligands while the alcohol was taken as a solvent. The ligands includedadipylhydroxamic acid (ADHA), p-phthalichydroxamic acid (PPHA), oxalohydroxamic acid (OXHA),butadihydroxamic acid (BDHA), o-phthalichydroxamic acid (OPHA), benzoylhydroxamic acid (BHA), etc.Measured at 25 deg C, the molar conductances in various modes are 13.00-21.05 S centre dot cm^2centre dot mol^(-1), which shows that rare-earth complexes are nonelectrolytes and the hydroxaminogroups of the complexes have taken part in bonding. Infrared spectra, ultraviolet spectra, nuclearmagnetic resonance (~1HNMR) spectra, and fluorescence spectra were used to investigate thecomplexes. Experiments have proved that the complexes of En^(3+)and Tb^(3+) with aromatic hydroxamicacids have good fluorescent characteristics.
基金
This Work was Financially Supported by the National Natural Science Foundation ofjiangxi Province (-1181).
