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A Novel Regeneration Method of Cu(0)-deposited TiO_2 Photocatalytic Film:Air-assisted Electrochemical Oxidation

A Novel Regeneration Method of Cu(0)-deposited TiO_2 Photocatalytic Film:Air-assisted Electrochemical Oxidation
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摘要 A rapid deactivation of TiO2 film was observed in the process of the photocatalytic degradation of formic acid in the presence of Cu(II) due to the deposition of Cu(0). A novel regeneration method, air-assisted electrooxidation, could efficiently retrieve the photocatalytic activity of the deact ivated film. HNO3 medium has a regeneration extent of 97.2% for first run, much higher than that of HCl and H2SO4 mediums. A rapid deactivation of TiO2 film was observed in the process of the photocatalytic degradation of formic acid in the presence of Cu(II) due to the deposition of Cu(0). A novel regeneration method, air-assisted electrooxidation, could efficiently retrieve the photocatalytic activity of the deact ivated film. HNO3 medium has a regeneration extent of 97.2% for first run, much higher than that of HCl and H2SO4 mediums.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第11期1127-1130,共4页 中国化学快报(英文版)
关键词 PHOTOCATALYSIS ELECTROOXIDATION REGENERATION TiO2 formic acid copper. Photocatalysis electrooxidation regeneration TiO2 formic acid copper.
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