摘要
The title complex, [CuLaL 5(phen)(C 2H 5OH)] 2(where L= α methylacrylato; phen=1,10 phenanthroline), has been prepared and its structure has been determined by X ray diffraction analysis. The complex crystallizes in triclinic system with space group P 1 . Crystal data: a =1 2725(3) nm, b =1 4421(4) nm, c =1 2109(2) nm, α =109 48(2)°, β =115.26(2)°, γ=66 42(2)°. The complex is a discrete tetranuclear CuLaLaCu molecule bridged by α methylacrylato groups. Magnetic property of the complex was also measured and discussed.
The title complex, [CuLaL 5(phen)(C 2H 5OH)] 2(where L= α methylacrylato; phen=1,10 phenanthroline), has been prepared and its structure has been determined by X ray diffraction analysis. The complex crystallizes in triclinic system with space group P 1 . Crystal data: a =1 2725(3) nm, b =1 4421(4) nm, c =1 2109(2) nm, α =109 48(2)°, β =115.26(2)°, γ=66 42(2)°. The complex is a discrete tetranuclear CuLaLaCu molecule bridged by α methylacrylato groups. Magnetic property of the complex was also measured and discussed.
