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Polyaniline–polypyrrole nanocomposites using a green and porous wood as support for supercapacitors

Polyaniline–polypyrrole nanocomposites using a green and porous wood as support for supercapacitors
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摘要 Wood is an ideal type of support material whose porous structure and surface functional groups are beneficial for deposition of various vip substances for different applications. In this paper, wood is employed as a porous support, combined with two kinds of conductive polymers (i.e., polyaniline (PANI) and polypyrrole (PPy)) using an easy and fast liquid polymerization method. Scanning electron microscope observations indicate that the PANI-PPy complex consists of nanoparticles with a size of -20 nm. The interactions between oxyge containing groups of the wood and the nitrogen composition of PANI-PPy were verified by Fourier transform infrared spectroscopy. The self-supported PANI-PPy/ wood composite is capable of acting as a free-standing supercapacitor electrode, which delivers a high gravimetric specific capacitance of 360 F· g^-1 at 0.2 A·g^-1. Wood is an ideal type of support material whose porous structure and surface functional groups are beneficial for deposition of various vip substances for different applications. In this paper, wood is employed as a porous support, combined with two kinds of conductive polymers(i.e., polyaniline(PANI) and polypyrrole(PPy))using an easy and fast liquid polymerization method.Scanning electron microscope observations indicate that the PANI–PPy complex consists of nanoparticles with a size of ~20 nm. The interactions between oxygencontaining groups of the wood and the nitrogen composition of PANI–PPy were verified by Fourier transform infrared spectroscopy. The self-supported PANI–PPy/wood composite is capable of acting as a free-standing supercapacitor electrode, which delivers a high gravimetric specific capacitance of 360 F·g–1 at 0.2 A·g–1.
作者 Jian LI Yue JIAO
出处 《Frontiers of Agricultural Science and Engineering》 2019年第2期137-143,共7页 农业科学与工程前沿(英文版)
基金 supported by the Fundamental Research Funds for the Central Universities(2572018AB09) the National Natural Science Foundation of China(31470584)
关键词 WOOD POLYPYRROLE POLYANILINE SUPERCAPACITORS NANOCOMPOSITES wood polypyrrole polyaniline supercapacitors nanocomposites
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