期刊文献+

不同合成方法对单辛基磷酸钛性质的影响

Different properties shown in titanium bis(mono-octyl phosphate) prepared by three different synthetic methods
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摘要 本文论述了新型离子交换剂──单辛基磷酸钛的三种不同合成方法,研究了不同 合成方法对产物结晶行为、比表面和孔径的影响关系.结果表明,直接沉淀法制得高比表面 积的无定型产物,HF酸重结晶法可得到高结晶度、低比表面积的产物.回流法所得产物的 表面性质介于上述两者之间. In this paper is made a comparison of three different methods for synthesis of titanium his (mono-octyl phosphate) the ion-exchanger in an attempt to find out the differences in crystallization behavior and specific surface area and pore diameter of the products thus prepared. It is found that amorphous products with high specific surface area are obtained in the course of direct precipitation; products with low specific surface area and high crystallization degree are obtained when re-crystallized by HF acid; and products with surface behaviors in between the two mentioned above is obtained when the reflux process is used.
出处 《汕头大学学报(自然科学版)》 2000年第2期55-58,共4页 Journal of Shantou University:Natural Science Edition
关键词 合成方法 单辛基磷酸钛 结晶行为 离子交换剂 比表面积 孔径 结晶度 titanium his (mono-octyl phosphate) crystallization property
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参考文献5

  • 1Maya L and Dams P O.Bis (octadecyl phosphate) Zirconium (Ⅳ) novel support for reversed phasechromatography[].J Chrom.1980
  • 2Trarnota M and Nomura Y.Catalytic oxidation of proper over Zirconium phosphate[].Journal of Catalysis.1981
  • 3Alberti G and Costantino U and Lucini Giovagndtti M L.Synthesis and ion-exchange properties ofZirconium (Ⅳ) Bis (carboxymethanephosphate ) ──A new organic-inorganic ion exchanger[].JChrom.1979
  • 4Clearfield A and Thakur D S.The acidity of zirconium phosphate in relation to their activity in thedehydration of cyclohexanol[].Journal of Catalysis.1980
  • 5Alberti G and Costantino U.Crystalline Zr (R-PO3)2 and Zr (R - OPO3)2 compounds[].Journal of Inorganic and Nuclear Chemistry.1978

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