摘要
本文利用计算机模拟溶液平衡法,将逐级配合物相互交错的配位平衡分解为各自独立的单一平衡,给出控制的实验参数,可方便地用于配位显色反应的等色点,并配合等色点—平衡移动法测得配合物稳定常数。
In this paper,computer is used to simulate the solution equilibr- ium,so the overlapping stepwise equilibria can be resolved into single equilibrium and the data of experimental conditions can be given.Because this,the isosbestie points of a coordinate reaction can be obtained easily,aud the stepwise stability constants of complexes cau be cac-ulated through experim ental data by the isosdesfic points- equilibriu shift method.
关键词
等色点
平衡移动
配位平衡
计算机
computer Simulation isosbestic points-equilibrium shift method
solut ion equilibrium
