摘要
本文研究了水溶性和油溶性阻聚剂对第Ⅱ类动力学乳液聚合的影响(以苯乙烯乳液聚合为例).实验结果表明阻聚剂对胶粒的形成及增长有明显的影响.推导出反映这些影响的数学模型,并对阻聚剂的影响进行了模拟研究,指出阻聚剂的这些行为在工业乳液聚合中的严重性.
The behaviour of water soluble and monomer soluble inhibitors in the emulsion polymerization for Case I systems (e. g. vinyl acetate and vinyl chloride) has been studied. The behaviour of monomer soluble inhibitors is shown to be quite different from that observed in Case II emulsion polymerization systems. Model predictions on the effect of these inhibitors on polymer particle nucleation and growth rate are shown to be in satisfactory agreement with experimental.
出处
《化工学报》
EI
CAS
CSCD
北大核心
1989年第4期410-416,共7页
CIESC Journal
