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富勒烯(C_(60)/C_(70))与三苯基胺间的光诱导电子转移过程研究 被引量：5

Photoinduced Electron Transfer Processes between Triphenylamine and Fullerenes (C_(60)/C_(70))
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摘要 用激光光解方法研究了富勒烯 (C60 /C70 )与三苯基胺 (TPA)间的光诱导电子转移过程 .在近红外区 ,观测到TPA阳离子自由基 ,富勒烯 (C60 /C70 )激发三线态和阴离子自由基 .在苯腈溶液中 ,利用瞬态谱测定了电子从TPA转移到富勒烯 (C60 /C70 )激发三线态的量子转化产率 (Φet)和电子转移常数 (ket) . Photoinduced electron transfer processes between fullerenes (C-60/C-70) and triphenylamine (TPA) have been studied by nanosecond laser flash photolysis. Quantum yields (Phi(et)) and rate constants (k(et)) of electron transfer from TPA to excited triplet state of fullerenes (C-60/C-70) in benzonitrile have been evaluated by observing the transient absorption bands in the near-IR region where the excited triplet state, radical anion of fullerenes (C-60/C-70) and radical cations of TPA appear.
作者 曾和平
机构地区 华南师范大学化学系
出处 《化学学报》 SCIE CAS CSCD 北大核心 2002年第9期1543-1547,共5页 Acta Chimica Sinica
基金 国家自然科学基金 (No .2 0 0 710 12 ) 教育部高校骨干教师资助计划 (No .2 0 0 0 6 5 ) 广东省自然科学基金 (No .0 0 0 70 0 )资助项目
关键词 三苯基胺 光诱导电子转移 富勒烯 瞬态谱 碳60 碳70 激光光解 photoinduced electron transfer fullerenes (C-60/C-70) transient absorption bands
分类号 O621.25 [理学—有机化学]
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参考文献14

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同被引文献29

  • 1曾和平.Photoinduced Electron Transfer between N,N,N′,N′-Tetra-(p-methylphenyl)-4,4-diamino-1,1′-diphenyl Ether (TPDAE) and Fullerenes (C_(60)/C_(70)) by Laser Flash Photolysis[J].Chinese Journal of Chemistry,2002,20(12):1546-1551. 被引量：1
  • 2宋礼成,延卫,胡青眉,刘友婴,贺天喜.富勒烯C_（60）的柱色谱分离法研究[J].无机化学学报,1995,11(2):176-179. 被引量：4
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  • 10Atwood, J. L. , G. A. Koutsantonls, C. L. Raston. Purifieation of C60 and C70 by Selective Complexation with Calixarenes [J]. Nature, 1994, 368:229-231.

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化学学报
2002年 第9期

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