摘要
以己二酸为原料,加热后脱羧并失水生成环戊酮。在钨酸钠、磺基水杨酸和十六烷基三甲基溴化铵催化下,以环戊酮为原料,用30%过氧化氢作为氧化剂,合成戊二酸,产率为52.21%。实验采用绿色合成戊二酸的方法,安全环保。
Using adipic acid as raw material,cyclopentanone was synthesized by decarboxylation and dehydration. Glutaricacid was synthesized by sodium tungstate and sulfosalicylic acid catalyzed oxidation cyclopentanone with 30% hydrogenperoxide in the presence of hexadecyl trimethyl ammonium bromide as a phase transfer catalyst. The yield of reaction was52.21%. The experiment used method of green synthesis to obtain glutaric acid, with green environmental protection.
作者
卢心愿
李闪闪
卢方方
李公春
王宏胜
LU Xin-yuan;LI Shan-shan;LU Fang-fang;LI Gong-chun;WANG Hong-sheng(Key Laboratory of Chemo/Biosensing and Detection, College of Chemistry and Chemical Engineering,Xuchang University, Xuchang 461000, China）t：)
出处
《安徽化工》
CAS
2017年第6期33-35,共3页
Anhui Chemical Industry
基金
河南省高等学校重点科研项目(项目编号:16A150062)
许昌学院转型发展特色项目资助
关键词
环戊酮
过氧化氢
戊二酸
绿色合成
cyclopentanone
hydrogen peroxide
glutaric acid
green synthesis
