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Ba_(0.98)Ce_(0.9)Y_(0.1)O_(3-α)固体电解质的离子导电性 被引量:5

Ionic conduction in Ba_(0.98)Ce_(0.9)Y_(0.1)O_(3-α) solid electrolyte
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摘要 用高温固相反应法制备了非化学计量性固体电解质Ba0 .98Ce0 .9Y0 .1O3 -α,分别用氢浓差电池及氧浓差电池方法研究了在 60 0~ 10 0 0℃范围Ba0 .98Ce0 .9Y0 .1O3 -α的离子导电特性。结果表明 ,Ba0 .98Ce0 .9Y0 .1O3 -α固体电解质在氢气气氛中几乎为纯质子导体 。 Ba 0.98 Ce 0.9 Y 0.1 O 3-α solid electrolyte has been prepared by high temperature solid state reaction. Its ion conducting characteristics have been investigated by means of hydrogen and oxygen concentration cells between 600℃ and 1000℃. It was found that the solid electrolyte exhibited almost a pure protonic conduction under hydrogen atmosphere, where as it was a mixed conductor of oxide ion and electron hole.
出处 《功能材料》 EI CAS CSCD 北大核心 2002年第4期418-419,421,共3页 Journal of Functional Materials
基金 国家自然科学基金资助项目 (2 0 1 71 0 34)
关键词 Ba0.98Ce0.9Y0.1O3-α 固体电解质 离子导电性 钙钛矿型氧化物 质子导体 Ba 0.98 Ce 0.9 Y 0.1 O 3-α solid electrolyte perovskite type oxide proton conductor
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