摘要
研究了在无金属参与条件下芳基溴化物与烷基硫醇的C—S交叉偶联反应.研究表明在室温、KO^tBu强碱作用条件下,各种缺电子的芳基溴化物与烷基硫醇均可以顺利地发生C—S交叉偶联反应,高产率地得到了一系列烷基芳基硫醚类产物.本研究同时对非金属参与的偶联反应机理进行了探讨.
The C—S cross-coupling of aryl halides with alkyl thiols under transition metal-free conditions was investigated. Good to excellent yields can be obtained for a variety of electron-poor aryl halides with alkyl thiols in the presence of KO^tBu even at room temperature. The mechanisms for transition metal-free coupling reactions are discussed.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2017年第6期1556-1559,共4页
Chinese Journal of Organic Chemistry
基金
supported by the National Natural Science Foundation of China(No.21101085)
the Natural Science Foundation of Liaoning Province(No.2015020196)
the Fushun Science&Technology Program(No.FSKJHT 201423)
the Liaoning Excellent Talents Program in University(No.LJQ2012031)
the Talent Scientific Research Fund of Liaoning Shihua University(No.2016XJJ-006)~~
