摘要
采用一步法制备出2-硫醇基甲基苯并咪唑锌(MMBZ),通过FTIR,UV-Vis,XRD,TG-DSC对其进行检测和表征,揭示出MMBZ的微观结构和内在规律性。FTIR揭示了MMBZ分子内部的各元素之间的化学键键型,确定最终产物为MMBZ。UV-Vis检测出MMBZ在219.6,245.5和302.2nm有三个吸收峰,分别为MMBZ分子中S—C、苯环、含N五元杂环的n→σ*,π→π*,π→π*的电子跃迁产生的,为企业MMBZ产品质量检测,推测MMBZ的结构提供实验依据。XRD谱图发现MMB作为MMBZ的配体,仍然保留其单元基本结构,MMBZ分子呈非晶态结构。TG-TG-DSC检测出MMBZ的质量变化与热效应两种信息,在167.5,155.3,253.7,324.8,391.3℃吸热峰,分别为杂质溶剂分解峰、相变峰、分解峰。一步法制备环保复合型橡胶防老剂MMBZ,方案切实可行,本研究通过检测结果推测MMBZ结构,关联MMBZ的性能,探究其防橡胶老化机理,开拓MMBZ应用范围,提供基础实验数据。
In the study,zinc methyl mercaptobenzimidazole（MMBZ）was synthesized by one-step method.MMBZ was detecued and characterized by FTIR,UV-Vis,XRD,TG-DSC.Its micro-structure and intrinsic regularity were revealed.Chemical bond types into MMBZ molecule were revealed by FTIR.The final product was determined MMBZ.There absorption peaks were detected by UV-Vis at 219.6,245.5,302.2nm respectively,due to n→σ＊,π→π＊,π→π＊electronic transitions,led by S—C,benzene and five element heterocyclic in MMBZ molecule.It could provide experimental basis with enterprise to test MMBZ product quality and speculate its structure.It was shown that MMB was a ligand of MMBZ,and its basic structure of MMB was retained still by XRD spectra.The structure of MMBZ molecule was amorphous.Two kinds of information were detected with TG-DSC as quality change and thermal effect.There were five absorption peaks of 67.5,155.3,253.7,324.8,391.3 ℃,due to impurity solvent decomposition peak,phase transition peak and decomposition of MMBZ respectively.The scheme of one step preparation of composite environment-friendly rubber antioxidant MMBZ was feasible.The structure of MMBZ could be speculated by results of its detecting.It could provide the basis of experimental data on association MMBZ performance,exploring its anti-aging mechanism and extending the scope of MMBZ application.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2016年第12期4013-4016,共4页
Spectroscopy and Spectral Analysis
基金
国家自然科学基金项目(21103076)
河南省高等学校重点科研项目(16B530001)资助
