摘要
采用传统的固相反应法制备(Sr1-xBax)La4Ti4O15(x=0~1,BSLT)微波介质陶瓷,并对其物相组成、晶体结构及微波介电性能进行分析。研究结果表明,Ba2+含量的增加降低了BSLT陶瓷的烧结温度,陶瓷的主晶相为(Sr,Ba)La4Ti4O15,并伴随有第二相La2TiO5的生成。在微波频率下,随Ba2+含量的增加,BSLT陶瓷的微波介电常数εr及品质因数与频率之积Q×f值先增大后减小,谐振频率温度系数τf为(-4^-11)×10-6/℃,优化出(Sr0.9Ba0.1)La4Ti4O15陶瓷具有最佳微波介电性能:εr=47.5,Q×f=31 582GHz,τf=-7.5×10-6/℃。
(Sr1-xBax)La4Ti4O15(x=0~1,BSLT)microwave dielectric ceramics were fabricated by the conventional solid state reaction method.The phase composition,microstructure and microwave dielectric properties of BSLT ceramics were investigated.The results show that adding Ba2+into BSLT ceramics would help to lower sintering temperature.The La2TiO5 main phase was observed in the ceramics besides the second phase of(Sr,Ba)La4Ti4O15.With increasing the content of Ba2+,the dielectric constant and the value of Q×fincreases firstly and then decreases and the value of the temperature coefficient of resonance frequency ranges from-4×10-6/℃ to-11×10-6/℃.The ceramic with composition of(Sr0.9Ba0.1)La4Ti4O15 shows the optimal dielectric properties:εr=47.5,Q×f=31 582 GHz,τf=-7.5×10-6/℃.
出处
《压电与声光》
CAS
CSCD
北大核心
2016年第2期207-211,216,共6页
Piezoelectrics & Acoustooptics
基金
陕西省科学技术研究发展计划基金资助项目(2014K08-10)
航空科学基金资助项目(20140853013)