摘要
Novel segmented urethane-siloxane copolymers were synthesized by a two-step bulk polymerization procedure using 4,4'-methylenediphenyl diisocyanate( MDI) and 1,4-butanediol( BDO)as the hard segment components and novel polypropyleneoxide polyether( PPO) blocked polydimethylsilxoane( PDMS) α,ω-dihydroxy-( PPO-PDMS-PPO) as the soft segment component,where the hard segment content was 30% by weight,and the molar ratio of NCO / OH was 1. 02. A series of urethane-siloxane copolymers were prepared from different molecular weights of α,ω-dihydroxy-( PPO-PDMS-PPO). The soft segments were different in the molecular of PDMS block segment. Chemical structure,morphology,mechanical properties,surface properties and thermal properties of thermoplastic polyurethane( TPU) were investigated by Fourier transform infrared spectroscopy( FT-IR),scanning electron microscopy and energy dispersive X-ray spectroscopy( SEM-EDX),mechanical properties( MP) test,water contact angle( WCA) test,differential scanning calorimetry( DSC),thermogravimetric analysis( TGA), respectively. According to the obtained results, the hydrophobicity of silicone modified TPU promoted,surface WCA increased from 73° to 120°. Low temperature resistant performance was improved,and the glass transition temperature decreased from- 44. 2℃ to- 120. 8℃. Thermal stability was also improved,the beginning temperature of thermal degradation increased from 281 ℃to 299 ℃.
Novel segmented urethane-siloxane copolymers were synthesized by a two-step bulk polymerization procedure using 4,4＇-methylenediphenyl diisocyanate（ MDI） and 1,4-butanediol（ BDO）as the hard segment components and novel polypropyleneoxide polyether（ PPO） blocked polydimethylsilxoane（ PDMS） α,ω-dihydroxy-（ PPO-PDMS-PPO） as the soft segment component,where the hard segment content was 30% by weight,and the molar ratio of NCO / OH was 1. 02. A series of urethane-siloxane copolymers were prepared from different molecular weights of α,ω-dihydroxy-（ PPO-PDMS-PPO）. The soft segments were different in the molecular of PDMS block segment. Chemical structure,morphology,mechanical properties,surface properties and thermal properties of thermoplastic polyurethane（ TPU） were investigated by Fourier transform infrared spectroscopy（ FT-IR）,scanning electron microscopy and energy dispersive X-ray spectroscopy（ SEM-EDX）,mechanical properties（ MP） test,water contact angle（ WCA） test,differential scanning calorimetry（ DSC）,thermogravimetric analysis（ TGA）, respectively. According to the obtained results, the hydrophobicity of silicone modified TPU promoted,surface WCA increased from 73° to 120°. Low temperature resistant performance was improved,and the glass transition temperature decreased from- 44. 2℃ to- 120. 8℃. Thermal stability was also improved,the beginning temperature of thermal degradation increased from 281 ℃to 299 ℃.
